1. Main contents of the project
Establishing an aramid fiber and product processing base
2. Main characteristics and current use of aramid fiber
The full name of aramid fiber is aromatic. Polyamide fiber, a new type of high-tech synthetic fiber, has excellent properties such as ultra-high strength, high modulus, high temperature resistance, acid and alkali resistance, and light weight. Its strength is 5 to 6 times that of steel wire, and its modulus is that of steel wire or glass. It is 2 to 3 times that of fiber, twice as tough as steel wire, and weighs only about 1/5 of steel wire. It does not decompose or melt at a temperature of 560 degrees. It has good insulation and anti-aging properties and has a long life cycle. It is a kind of high-temperature flame-retardant fiber with high strength, high modulus, low density and good wear resistance. It has high technical content, high added value, excellent mechanical, chemical stability and mechanical properties. It can not only be used alone for various Structural materials and functional materials, and can also be used in combination with other materials. In addition, it also has good resilience and sealing performance, and is not harmful to human health and the environment. It can be used for sealing media such as water, oil, hydrocarbons, and medium-strength acids and alkalis. The gaskets produced have excellent Excellent sealing performance and creep relaxation resistance. It can be used as a substitute for asbestos in friction sealing materials, high-performance heat-resistant insulation paper and reinforced composite materials.
1. Main varieties of aramid
Commercial aramid mainly includes meta-aramid and para-aramid Meta-aramids and meta-aramids mainly include DuPont’s Nomex, Teijin’s Conex, etc.; para-aramids mainly include Kevlar (DuPont), Technora (Teijin), Twaron (Teijin), etc.
2. Current status of research and application of aramid functional textiles
The unique physical and chemical properties of aramid fiber make it widely used in high temperature resistant, flame retardant, wear-resistant and high-strength functional textiles. Research on it is also in the ascendant around the world. New functional textiles are emerging one after another, and their application fields are constantly expanding.
Aramid fiber is an important national defense and military material. In order to meet the needs of modern warfare, currently, body armor in developed countries such as the United States and the United Kingdom are made of aramid. Aramid bulletproof The lighter weight of clothing and helmets has effectively improved the army’s rapid response capability and lethality. During the Gulf War, U.S. and French aircraft used aramid composite materials extensively. In addition to military applications, it is now widely used as a high-tech fiber material in various aspects of the national economy such as aerospace, electromechanical, construction, automobiles, and sporting goods. In terms of aviation and aerospace, aramid fiber saves a lot of power fuel due to its light weight and high strength. According to foreign data, during the launch process of a spacecraft, every kilogram of weight reduced means a cost reduction of US$1 million. . In addition, the rapid development of science and technology is opening up more new civilian spaces for aramid. According to reports, currently, aramid products account for about 7 to 8% of body armor, helmets, etc., aerospace materials and sports materials account for about 40%; tire frame materials, conveyor belt materials, etc. account for about 20%. High-strength ropes and other aspects account for about 13%.
2.1 Aramid flame retardant series textiles
Although aramid fiber It has good heat resistance and flame retardancy, but is relatively expensive. Secondly, due to the high molecular crystallinity and strong intermolecular binding force, dyeing is difficult. The high price and difficulties in dyeing have inhibited its output and variety development to some extent. As a result, various aramid blended flame-retardant fabrics have been researched and developed to improve the dyeing effect and reduce product prices.
(1) Aramid and wool blended flame-retardant fabric. Wool is a natural fiber with certain flame-retardant properties. The aramid staple fiber is first made into strips, and then mixed with tops to form Yarn and then weaved. When the proportion of aramid blend exceeds 30%, its limiting oxygen index reaches more than 28. The fabric can achieve good and long-lasting flame retardant properties without flame retardant finishing, and can reduce costs without affecting the appearance and comfort of the fabric. The blending ratio can be adjusted according to the purpose to achieve multi-functionality.
(2) Aramid and cotton blended flame-retardant fabrics are similar. In order to reduce costs and achieve multi-functional requirements, flame-retardant fabrics are made by blending aramid and cotton fibers in a certain proportion. Fabric. In the study of aramid and cotton fiber blends, the blending ratios of aramid and cotton are usually 80/20, 50/50, and 20/80. The continuation time, smoldering time, and damage length of these three blended fabrics before and after washing All meet the requirements of GB8965-88 level two or above, and the limiting oxygen index LOI value is also greater than the 28 standard with flame retardant requirements. As the aramid content increases, the LOI value also increases. Among them, 80/20 fabric has excellent heat resistance and flame retardancy and can meet the national flame retardant clothing requirements without flame retardant finishing; 50/50 and 20/80 blended fabrics require Proban flame retardant finishing to achieve flame retardant clothing. fuel standard requirements.
(3) Flame-retardant fabric blended with aramid and flame-retardant viscose fiber. Flame-retardant viscose is a silicate-containing fibrous fiber. Its physical and mechanical properties are different from ordinary Viscose fibers are similar and can be processed into a variety of textiles. Aramid and flame-retardant viscose blended fabric has a soft feel, good fluffiness, drape, moisture absorption and breathability, high strength and abrasion resistance, good surface finish, color fastness and non-melting when exposed to fire. Excellent characteristics such as drops, which can meet the requirements of medium and medium range resistanceAnd, energy can be absorbed over a larger area, so its elasticity resistance is better.
The surface density of aramid weft-free cloth and the mass fraction of matrix resin are important factors affecting the elastic properties of its laminate. When the weft-free fabric has a smaller areal density and a lower matrix resin mass fraction, the elastic resistance of the laminate will be better.
2.8 aramid/carbon fiber non-woven fabric
Used The aramid/carbon fiber non-woven fabric produced by the puncture method has an oxygen barrier index LOI of 38~42 and a fire protection temperature of 700°C. Mainly used for fire-proof and heat-insulating interlinings, high-temperature dust filters, decorative interlinings, fire-splash covering cloths, etc.
2.9 Aramid/armor steel composite plate
Aramid Fiber-reinforced resin-based composite materials have the characteristics of light weight, high strength, good elasticity resistance, and excellent explosion-proof effect. Installing aramid fiber composite plates on armored steel can improve its anti-knock performance. The structure of the material will affect the shock wave attenuation effect of the material. Shock waves are more effectively attenuated when materials are arranged in order of decreasing wave impedance. Materials with a multi-layer structure have better attenuation effects than materials with a double-layer structure, and can obtain protective materials with excellent anti-knock properties.
3. Development direction of aramid fiber
According to the “Twelve During this period, my country’s kiloton-level para-aramid fiber production technology will achieve a breakthrough and enter a period of rapid growth, thereby driving the rapid development of related industries. Focusing on strategic emerging industries, major national economic construction projects, national defense and military industry, and material industry structure upgrades, the China Chemical Fiber Industry Association conducted a focused analysis of the demand for major downstream application fields, product self-sufficiency rates, and main varieties that need to be imported. In the next 10 years, domestic fields such as automobiles, communications, high-speed railways, aviation and protection will develop rapidly, and the demand for para-aramid fiber will be strong; at the same time, the industrial transfer of foreign downstream processing companies to China will also stimulate domestic production. Growth in demand for para-aramid. Domestic demand for para-aramid fiber will exceed 10,000 tons in 2015 and will exceed 20,000 tons in 2020. Among them, the domestic demand in 2015 is predicted to be 2,000 tons for general-purpose para-aramid filament, 1,000 tons for high-strength type, and 2,000 tons for high-model; 2,000 tons of para-aramid staple fiber; 3,000 tons of para-aramid pulp. In addition, by 2015, the domestic supply of para-aramid fiber will reach 50% and 80% by 2020.
IV. Aramid fiber product development
According to aramid special Based on the characteristics of the fabric, the following products can be developed:
1. Bulletproof camouflage uniforms, stab-proof vests, bulletproof and impact-resistant helmets, tank jumpsuits, bulletproof shields, racing suits, etc.;
2. Anti-cut clothing, explosive disposal clothing, anti-stab clothing, anti-cut bags, etc.;
3. Headgear, gloves , socks, etc.
4. Labor protection products for children and the elderly
5. Pajamas
6. Aramid non-woven fabrics
7. Public safety equipment, transportation safety packaging, and protective devices for vehicles and aircraft</p
